The quest is available from Nevusa Dark Brotherhood Sanctuary once you have completed the quest "A Lesson in Silence" and the first Sacrament quest. Speak with Nevusa, read the book then speak with Nevusa again.
There are 15 NPC's to be assassinated, this is a list and where to find them. Once you arrive at the location, the NPC can be identified as they will have a white eye icon above them. Once killed with the Blade of Woe they will disappear in a cloud of ash. They will then appear as a ghost inside the Sanctuary on a pedestal.
Once you complete the mission you will be awarded the Cadaverous Assassin outfit and the Litany of Blood furnishing, as well as some gold.
Litany of Blood Achievement Locations
|Name||Litany of Blood Clue||Zone||City||Location|
|Cesarel Hedier||I offer he whose dress is as cool as his demeanour and pate as barren as his heart.||Glenumbra||Daggerfall||Wanders around the streets between the Happy, Healthy Horses stables, The Rosy Lion inn, and the Outlaw's Refuge.|
|Bolaag||I offer she who greets death as a sister, her smile joyless and unflinching.||Rivenspire||Shornhelm||Walks between the Guild Merchants and the Merchants at the Southern Gate. Will stop to do some dagger juggling near merchant stands.|
|Alix Edette||I offer she who peers from behind a crimson curtain and marred her face to hide her nature.||Stormhaven||Wayrest||Walks the harbour to the Southeast. Sometime on the docks, sometimes up on the roads near the warehouses.|
|Ebrayd||I offer he who leaves a trail of neat black ropes dangling over a golden cage.||Alik'r Desert||Sentinel||Walks between the Crafting Stations and the cliffs near the guard tower just north of the crafting stations.|
|Berea||I offer she whose heart bears many scars, but does not fear to wear them proudly.||Bangkorai||Evermore||Walks between Evermore Wayshrine in the graveyard, The Stalls, a road to Tordrak's Eldritch Emporium, and sitting just outside the Anchor Point's Inn.|
|Cimalire||I offer she who reflects the heavens in her gaze and dress, drifting from dance to dance.||Auridon||Skywatch||Walks a circuit around the courtyard area between the Mage's and the Fighter's Guilds. Will sometimes stop to join the Skywatch Celebrants watching the entertainers.|
|Caraleth||I offer she who surveys the market beneath an auburn veil and keeps silver close to her heart.||Greenshade||Marbruk||Walks a path from the Wayshrine to the Fighter's Guild, going through the merchants. Will stop to watch entertainers.|
|Dirdelas||I offer he who is as aged and gnarled as the trees, his back bowed but not bent.||Grahtwood||Elden Root||Walks between the Elder Root Wayshrine and the Outside Inn.|
|Sihada||I offer she who sweeps away the seasons with straw and the swish of her tail.||Malabol Tor||Vulkwasten||Walking around the town with a broom. It is a really small town. Hardest part is getting away from other NPCs.|
|Dablir||I offer he who clothes his stripes of brown with stripes of gold.||Reaper's March||Rawl'Kha||Walks around the market and then south past the city wall near the weaponsmith.|
|Hakida||I offer she who bears time at her waist, but for whom age has not robbed her golden crown.||Eastmarch||Windhelm||She can be found walking around the Mages Guild or a circuit of the Konunleikar festivities, past The Sober Nord Tavern, around the Windhelm Bank, and down past Oaken-Hull's Emporium.|
|Eldfyr||I offer he whose arms are coiled and stained with the ink and weeds of the sea.||The Rift||Riften||Hangs around near the market and around the market|
|Dinor Girano||I offer he who is silver, ash, and fire, draped in copper filigree.||StoneFalls||Davon's Watch||Walks between the Fighter's Guild, the bridge in the centre of town, and the Mage's Guild. Can also be found walking in market.|
|Cindiri Malas||I offer she who marches beneath a red crest and wields winding steel.||Deshaan||Mournhold||"Red crest" refers to her red-plumed helmet. Found near the bank.|
|Gideelar||I offer she who is caked in mud but wears a halo of bone, bright and untouched by mire.||Shadowfen||Stormhold||She can be found wandering the dotted path on the map, southwest of the Stormhold Wayshrine, the lower dotted path farther SW, or near the bank on the semi-circular road between the bank and wayshrine. She can be found shovelling.|
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